Although 1.0.1. is the oldest version currently covered by Bitcoin Core's extensive CI, Debian Bookwork ships 0.9.2 and #194 introduces test coverage for even older versions. 0.7 has been required since #88.
The CI run of https://github.com/Sjors/bitcoin/pull/100 @ 3d55222 previously checked Bitcoin Core CI against 1.0.1 as the minimum. Lowering the minimum further should not be a problem for that CI.